Kinetic Studies on the acid catalyzed reaction of hydroxamic acids in beta-cyodextrin/surfactant mixed systems

Kallol K.Ghosh; Pokhraj Shama; Samiksha Taramkar; Santosh Kumar Sar

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Kinetic Studies on the acid catalyzed reaction of hydroxamic acids in beta-cyodextrin/surfactant mixed systems

机译：β-环糊精/表面活性剂混合体系中异羟肟酸的酸催化反应动力学研究

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摘要

The acid catalyzed hydrolysis of two N-substituted hydorxamic acids (C_6H_5CON(OH)R',R'=C_6H_5(PBHA),R'=C_6H_5CH_2(BBHA)) in mixed systems containing beta-cyclodextrin (beta-CD0 and asurfactnt (sodium docdecyl surlfate,SDS) has been studied.the reactions are inhibited by beta-CD.Teh inhibition is attributed to the formation of inclusion complex and competition between the micellization and complexation processes.

机译：在含有β-环糊精（β-CD0和表面活性剂（钠） β-CD对反应有抑制作用。该抑制作用归因于包合物的形成以及胶束化和络合过程之间的竞争。

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《Reaction kinetics & catalysis letters》 |2004年第1期|共8页
作者
Kallol K.Ghosh; Pokhraj Shama; Samiksha Taramkar; Santosh Kumar Sar;
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正文语种 eng
中图分类化学动力学、催化作用;
关键词
Hydroxamic acids; Kinetics; hydrolysis; micelles;

机译：异羟肟酸;动力学;水解;胶束;

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1. Kinetic Studies on the acid catalyzed reaction of hydroxamic acids in beta-cyodextrin/surfactant mixed systems [J] . Kallol K.Ghosh, Pokhraj Shama, Samiksha Taramkar, Reaction kinetics & catalysis letters . 2004,第1期

机译：β-环糊精/表面活性剂混合体系中异羟肟酸的酸催化反应动力学研究
2. Synthetic reactions using organometallics in water. Aldol and allylation reactions catalyzed by Lewis acid-surfactant-combined catalysts/Bronsnted acids systems [J] . Kei Manabe, Yuichiro Mori, Satoshi Nagayama, Inorganica Chimica Acta . 1999,第1期

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3. Kinetic effects of surfactant/polymer mixtures upon acidic hydrolysis of hydroxamic acids [J] . Ghosh Kallol K., Pandey Alka Journal of Dispersion Science and Technology . 1999,第6期

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4. A DFT Study of the Isomerization Reactions of Aromatics Catalyzed by Acidic Zeolites [C] . X. Rozanska, R.A. van Santen, F. Hutschkaa, IZC;International zeolite conference . 2001

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5. Fundamental reaction kinetics studies of acid-catalyzed biomass conversion reactions into chemicals and fuels. [D] . Mellmer, Max A. 2016

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6. Reactions of N-Benzyloxycarbamate Derivatives with Stabilized Carbon Nucleophiles-A New Synthetic Approach to Polyhydroxamic Acids and Other Hydroxamate Containing Mixed Ligand Systems [O] . Yuan Liu, Hollie K. Jacobs, Aravamudan S. Gopalan -1

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Kinetic Studies on the acid catalyzed reaction of hydroxamic acids in beta-cyodextrin/surfactant mixed systems

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