Construction of benzoacarbazole derivatives via Diels-Alder reaction of arynes with vinylindoles

Wu Lijun; Huang Hui; Dang PanLiang YunPi Shaofeng

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Construction of benzoacarbazole derivatives via Diels-Alder reaction of arynes with vinylindoles

机译：芳烃与乙烯基吲哚的Diels-Alder反应构建苯并a咔唑衍生物

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A new protocol for a highly efficienct and versatile Diels-Alder reaction of vinylindoles with arynes (generated form 2-(trimethylsilyl)aryl triflate) has been developed. Various functionalized benzoacarbazoles were afforded in good to perfect yields via 4 + 2 cycloaddition/aromatization.

机译：已经开发了一种用于乙烯基吲哚与芳烃（生成形式2-（三甲基硅基）芳基三氟甲磺酸酯）的高效和通用Diels-Alder反应的新方案。通过[4 + 2]环加成/芳构化反应，各种官能化苯并[a]咔唑的收率良好至完美。

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《RSC Advances》 |2015年第79期|64354-64357|共4页
作者
Wu Lijun; Huang Hui; Dang PanLiang YunPi Shaofeng;
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作者单位

Hunan Normal Univ, Key Lab Assembly & Applicat Organ Funct Mol, Minist Educ, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Hunan, Peoples R China;

Cent South Univ Forestry & Technol, Inst Appl Chem, Changsha 410004, Hunan, Peoples R China;

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正文语种英语
中图分类化学;
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1. ChemInform Abstract: New Diels‐Alder Reactions of 3‐Vinylindoles with an Aryne: Selective Access to Functionalized (a)Anellated Carbazoles. [J] . E. GONZALEZ, U. PINDUR, D. SCHOLLMEYER Chem Inform . 1996,第43期

机译：ChemInform Abstract: New Diels‐Alder Reactions of 3‐Vinylindoles with an Aryne: Selective Access to Functionalized (a)Anellated Carbazoles.
2. ChemInform Abstract: First Asymmetric Diels‐Alder Reactions in the Vinylhetarene Series: Cycloadditions with Vinylindoles to Enantiomerically Pure Carbazole Derivatives. [J] . U. PINDUR, G. LUTZ, W. MASSAL. SCHROEDER Chem Inform . 1993,第29期

机译：ChemInform Abstract: First Asymmetric Diels‐Alder Reactions in the Vinylhetarene Series: Cycloadditions with Vinylindoles to Enantiomerically Pure Carbazole Derivatives.
3. ChemInform Abstract: Diels‐Alder Reactions of Vinylindoles with Aryne and 1,4‐Benzoquinones: New Potential DNA Intercalators. [J] . U. PINDUR, L. PFEUFFER, M. EITELM. ROGGEM. HABER Chem Inform . 1991,第30期

机译：ChemInform Abstract: Diels‐Alder Reactions of Vinylindoles with Aryne and 1,4‐Benzoquinones: New Potential DNA Intercalators.
4. Tandem Diels-Alder Reactions of Arynes: New Method for the Synthesis of Large Poly cyclic Aromatic Compounds and Nanographenes [C] . Diego Pena, Alejandro Criado, Dolores Perez European Symposium on Organic Chemistry . 2009

机译：Arynes的串联Diels-Alder反应：用于合成大聚环芳族化合物和纳米的新方法
5. Novel polythiophene derivatives functionalized withconjugated side-chain pendants comprisingtriphenylamine/carbazole moieties for photovoltaic cellapplications† [O] . Hsing-JuWang, Jiann-Yu Tzeng, Chen-Wei Chou, 2014

机译：Novel polythiophene derivatives functionalized withconjugated side-chain pendants comprisingtriphenylamine/carbazole moieties for photovoltaic cellapplications†

Construction of benzoacarbazole derivatives via Diels-Alder reaction of arynes with vinylindoles

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