Access to C-branched sugars: Stereoselective synthesis of C3-C5-linked deoxy disaccharide and C-linked deoxy aza disaccharide mimetics via a ring-closing Metathesis protocol

Krishna PR; Manjuvani A; Srinivasulu G; Kunwar AC

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Access to C-branched sugars: Stereoselective synthesis of C3-C5-linked deoxy disaccharide and C-linked deoxy aza disaccharide mimetics via a ring-closing Metathesis protocol

机译：获得C支链糖：通过闭环复分解方案立体选择性合成C3-C5连接的脱氧二糖和C连接的脱氧氮杂二糖模拟物

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摘要

RCM mediated stereoselective synthetic approaches for the branched C-C disaccharide and its aza analog via Ring Closing Metathesis protocol are described.

机译：描述了通过闭环复分解方案对支链C-C二糖及其氮杂类似物进行RCM介导的立体选择性合成方法。

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来源
《Letters in organic chemistry》 |2008年第6期|共8页
作者
Krishna PR; Manjuvani A; Srinivasulu G; Kunwar AC;
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正文语种 eng
中图分类有机化学;
关键词
C-C-disaccharide; C-linked aza disaccharide; ring-closing metathesis; cis-dihydroxylation; BARBIER-TYPE ALLYLATIONS; ALLYLIC ALCOHOL SYSTEMS; AQUEOUS-MEDIA; NATURAL-PRODUCTS; EMPIRICAL RULE; STEREOCHEMISTRY; GLYCOBIOLOGY; METHYLENE; OXIDATION;

机译：C-C-二糖;C-连接的氮杂二糖;闭环易位;顺式二羟基化;阻隔型烯丙基化;烯丙醇体系;水介质;天然产物;经验规则;立体化学;糖生物学;亚甲基;氧化;

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专利

1. Access to C-Branched Sugars: Stereoselective Synthesis of C3-C5-Linked Deoxy Disaccharide and C-Linked Deoxy Aza Disaccharide Mimetics via a Ring-Closing Metathesis Protocol [J] . Palakodety R. Krishna Appalashetti Manjuvani Gannoju Srinivasulu Aajit C. Kunwar Letters in Organic Chemistry . 2008,第6期

机译：获得C支链糖：C3-C5连接的脱氧双糖和C连接的脱氧氮杂双糖模拟物的立体选择性合成，方法是通过封闭环复分解方案
2. Ring Closing Metathesis as an Efficient Protocol for the Stereoselective Synthesis of Spiro C-Linked 4-Deoxy Disaccharides [J] . Jakkidi J. Reddy*a Asra Beguma Pagadala Jayaprakasha Gangavaram V.M. Sharma†a and Ajit C. Kunwarb Letters in Organic Chemistry . 2008,第2期

机译：闭环易位作为螺旋C连接的4-脱氧二糖的立体选择性合成的有效协议。
3. Ring closing metathesis as an efficient protocol for the stereoselective synthesis of spiro C-linked 4-deoxy disaccharides [J] . Reddy JJ, Begum A, Jayaprakash P, Letters in organic chemistry . 2008,第2期

机译：闭环易位是螺-C-连接的4-脱氧二糖立体选择性合成的有效方案
4. SYNTHESIS OF 1,1'-α,α-DISACCHARIDES EN ROUTE TO LIPID A MIMETICS [C] . Adanitsch. F., Kosma P., Zamyatina A International Carbohydrate Symposium . 2013

机译：合成1,1'-α，α-二糖的途径，脂质的模拟物
5. Part I: The large-scale synthesis of hyaluronan disaccharides utilizing a mild cleavage of 2-amino-2-deoxy-D-glucoside methoxycarbonyl derivatives with methyltrichlorosilane and the application for the synthesis of carbohydrate polymers. Part II: The synthesis of models for use in studying the solution behavior of carbohydrates in a hydrophobic environment. [D] . Werner, Sara Lynn Adamski. 2001

机译：第一部分：利用2-氨基-2-脱氧-D-葡萄糖苷甲氧羰基衍生物与甲基三氯硅烷的温和裂解，大规模合成透明质酸二糖，并将其用于碳水化合物聚合物的合成。第二部分：用于研究碳水化合物在疏水环境中的溶解行为的模型的合成。
6. Synthesis of Disaccharides Containing 6-Deoxy-α-L-talose as Potential Heparan Sulfate Mimetics [O] . Jon K. Fairweather, Ligong Liu, Tomislav Karoli, 2012

机译：含6-脱氧-α-L-塔洛糖的二糖类潜在硫酸乙酰肝素模拟物的合成
7. Synthesis of Disaccharides Containing 6-Deoxy-a-L-talose as Potential Heparan Sulfate Mimetics [O] . Vito Ferro, Tomislav Karoli, Jon K. Fairweather, 2012

机译：含有6-脱氧-α-L-塔罗糖作为潜在硫酸乙酰肝素模拟物的二糖的合成

Access to C-branched sugars: Stereoselective synthesis of C3-C5-linked deoxy disaccharide and C-linked deoxy aza disaccharide mimetics via a ring-closing Metathesis protocol

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