Efficient synthesis of aromatic nitriles via cyanation of aryl bromides and K_4[Fe(CN)_6] catalyzed by a palladium(II) complex

Guo M.; Ge J.; Zhu Z.; Wu X.

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Efficient synthesis of aromatic nitriles via cyanation of aryl bromides and K_4[Fe(CN)_6] catalyzed by a palladium(II) complex

机译：通过钯（II）配合物催化芳基溴化物和K_4 [Fe（CN）_6]的氰化反应来高效合成芳族腈

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摘要

Cyanation of aryl bromides and K_4[Fe(CN)_6] were carried out in the presence of catalytic amounts of {[(PhCH_2O) _2P(CH_3)_2CHNCH(CH_3)_2]_2PdCl_2} (PdCl_2L_2) in DMF and a variety of Aromatic nitriles were obtained in good yields under aerobic conditions.

机译：在催化量的{[（PhCH_2O）_2P（CH_3）_2CHNCH（CH_3）_2] _2PdCl_2}（PdCl_2L_2）和DMF和多种芳族化合物存在下进行芳基溴化物和K_4 [Fe（CN）_6]的氰化反应在有氧条件下以高收率获得腈。

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《Letters in organic chemistry》 |2013年第3期|共3页
作者
Guo M.; Ge J.; Zhu Z.; Wu X.;
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正文语种 eng
中图分类有机化学;
关键词
Aromatic nitriles; Cyanation; Palladium(II) complex; Synthesis;

机译：芳香腈氰化钯（II）配合物合成;

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专利

1. Efficient synthesis of aromatic nitriles via cyanation of aryl bromides and K_4[Fe(CN)_6] catalyzed by a palladium(II) complex [J] . Guo M., Ge J., Zhu Z., Letters in organic chemistry . 2013,第3期

机译：通过钯（II）配合物催化芳基溴化物和K_4 [Fe（CN）_6]的氰化反应来高效合成芳族腈
2. The synthesis of poly-nitrile aromatic and oligopyridine ligands via palladium-catalyzed cyanation of aryl halides [J] . Veauthier JM, Carlson CN, Collis GE, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2005,第16期

机译：钯催化芳基卤化物的氰化反应合成多腈芳族和寡吡啶配体
3. Phosphinoferrocene amidosulfonates: Synthesis, palladium complexes, and catalytic use in pd-catalyzed cyanation of aryl bromides in an aqueous reaction medium [J] . í Schulz J., Císar?ová I., ?têpni?ka P. Organometallics . 2012,第2期

机译：膦二茂铁酰胺磺酸盐：在水性反应介质中，芳基溴化物在钯催化的氰化中的合成，钯配合物和催化应用
4. Synthesis of Aryl Phosphines by Palladium Catalyzed Phosphination of Aryl bromides and triflates with Triarylphosphines [C] . Fuk Yee Kwong International symposium for Chinese organic chemists . 2000

机译：钯芳溴化钯催化合成芳基膦酸磷酸酯和三芳基膦酸酯
5. Part I: The Study of 2-Aryl-1,3-Dithiane Derivatives As Pronucleophiles in Palladium-Catalyzed Allylic Alkylation and Propellylation Part II: Ligand-Free Palladium-Catalyzed Allylic Amintion of Hydrazone Derivatives Part III: Synthesis of Criegee Intermed [D] . Trongsiriwat, Nisalak. 2019

机译：第一部分：将2-芳基-1,3-二硫醚衍生物的研究作为钯催化的烯丙基烷基化和预选型第II部分：腙衍生物的配体钯催化烯丙基胺部分III：Criaegee中间的合成
6. A General Practical Palladium-Catalyzed Cyanation of (Hetero)aryl Chlorides and Bromides [O] . Todd D. Senecal, Wei Shu, Stephen L. Buchwald -1

机译：常规实用的钯催化的（杂）芳基氯化物和溴化物的氰化反应
7. Efficient cyanation of aryl bromides with K-4Fe(CN)(6) catalyzed by a palladium-indolylphosphine complex [O] . Yeung PY, Tsang CP, Kwong FY 2011

机译：钯-吲哚基膦配合物催化K-4 Fe（CN）（6）有效地芳基溴化物氰化

Efficient synthesis of aromatic nitriles via cyanation of aryl bromides and K_4[Fe(CN)_6] catalyzed by a palladium(II) complex

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