Thermal and morphological behavior of irradiated composite materials based on injection-moulded recycled polyethylene terephthalate

摘要

The effect of gamma irradiation and short glass fiber (SGF) on the thermal and morphological behavior of the recycled poly (ethylene terephthalate) (rPET) in the presence of reactive additive (epoxy resin, 2 wt ) has been investigated. Characterization of the resulted composites to evaluate the effect of incorporation the SGF and irradiation by means of differential scanning calorimetry, X-ray diffraction, thermal gravimetric analysis, and scanning electron microscopy (SEM). The results show that the SGF and epoxy resin behave as nucleating agents for the crystallization of rPET. A noticeable increase in the rPET thermal stability in the presence of both SGF and epoxy resin has been observed. Furthermore, the rPET melting temperature (T) slightly decrease in the presence of the SGF and remains nearly constant with the incorporation of the epoxy resin. On the other hand, the rPET crystallinity percent (X) decreases in the presence of SGF and gamma irradiation. The SEM showed that a layer of epoxy resin was coated onto the SGF in the rPET matrix. This coating layer raises the interfacial shear strength between the fiber and polymer matrix and also increases with gamma irradiation. (C) 2007 Wiley Periodicals, Inc.