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Novel preparation method of highly active Co/SiO2 catalyst for Fischer-Tropsch synthesis with chelating agents

机译:螯合剂费-托合成高活性Co / SiO2催化剂的新方法

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Co/SiO2 catalysts were prepared by the incipient wetness method using the aqueous Co nitrate solution modified with various organic acids and/or chelating agents followed by drying and calcination. After H-2 reduction at 773 K, the catalyst prepared with nitrilotriacetic acid (NTA) showed Fischer-Tropsch synthesis (FTS) activity ca. 3 times higher than the catalyst without additives under mild reaction conditions (503 K, 1.1 MPa).
机译:Co / SiO 2催化剂是通过初期湿润法制备的,先使用经各种有机酸和/或螯合剂改性的硝酸钴水溶液,然后进行干燥和煅烧。在773 K下H-2还原后,用次氮基三乙酸(NTA)制备的催化剂显示约Fischer-Tropsch合成(FTS)活性。在温和的反应条件下(503 K,1.1 MPa),该催化剂比不含添加剂的催化剂高3倍。

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