M?ssbauer spectroscopy monitoring the spin transition of a Fe~(II) 1D chain with a fluorinated 4-R-1,2,4-triazole

Antoine P. Railliet; Anil D. Naik; Aurelian RotaruYann Garcia

首页> 外文期刊>Hyperfine Interactions: Journal Devoted to Research in the Border Regions of Solid State, Atomic and Nuclear Physics >M?ssbauer spectroscopy monitoring the spin transition of a Fe~(II) 1D chain with a fluorinated 4-R-1,2,4-triazole

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M?ssbauer spectroscopy monitoring the spin transition of a Fe~(II) 1D chain with a fluorinated 4-R-1,2,4-triazole

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The spin transition properties of Fe(fletrz)_3(BF_4)_2?2H_2O are described. Fletrz (4-(2'-fluoroethyl)-4H-1,2,4-triazole) is a novel fluorine substituted 1,2,4-triazole ligand which forms 1D chain upon self-assembly with Fe~(II) ions. This coordination polymer exhibits reversible abrupt thermochromic spin transition that has been probed by SQUID magnetometry, variable temperature ~(57)Fe Mossbauer spectroscopy (77-300 K) and differential scanning calorimetry (100-300 K).

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来源
《Hyperfine Interactions: Journal Devoted to Research in the Border Regions of Solid State, Atomic and Nuclear Physics》 |2014年第3期|223-227|共5页
作者
Antoine P. Railliet; Anil D. Naik; Aurelian RotaruYann Garcia;
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作者单位

Institute of Condensed Matter and Nanosciences,Molecules, Solids and Reactivity (IMCN/MOST), Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium;

Department of Electrical Engineering and Computer Science, "Stefan cel Mare" University, University Street, No. 13, Suceava 720229, Romania;

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正文语种英语
中图分类固体物理学;分子物理学、原子物理学;原子核物理学、高能物理学;
关键词
~(57)Fe Mossbauer spectroscopy; Coordination polymers; Spin transition; 1; 2; 4-triazole;

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M?ssbauer spectroscopy monitoring the spin transition of a Fe~(II) 1D chain with a fluorinated 4-R-1,2,4-triazole

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