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3D nano-scale perovskite-based composite as Fenton-like system for efficient oxidative degradation of ketoprofen

机译:3D纳米钙钛矿基复合材料,作为类芬顿体系,可有效氧化降解酮洛芬

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摘要

Novel perovskite-based composite BiFeO3/carbon aerogel (BF0/CA) as heterogeneous Fenton-like catalyst with three-dimensional (3D) structure, nano-scaled size and high surface area was fabricated by a sol-gel method. Catalyst characterization showed nano BFO active sites were not simply placed on the surface of support CA, but grown along with the 3D structure of CA. The reactivity of catalyst was investigated by the oxidation of ketoprofen as a model pollutant, which exhibited efficient catalytic activity. Moreover, nano BFO/CA retained almost its high catalytic activity in wide pH range of 3-7, and had a very low iron leaching even in acidic condition.
机译:通过溶胶-凝胶法制备了新颖的钙钛矿基复合BiFeO3 /碳气凝胶(BF0 / CA),其为三维(3D)结构,纳米级尺寸和高表面积的非均相芬顿状催化剂。催化剂表征表明,纳米BFO活性位点不仅简单地置于支持物CA的表面上,而且与CA的3D结构一起生长。通过氧化酮洛芬作为模型污染物研究了催化剂的反应活性,该化合物表现出有效的催化活性。此外,纳米BFO / CA在3-7的宽pH范围内几乎保留了其高催化活性,即使在酸性条件下也具有非常低的铁浸出。

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