Eco-friendly synthesis of epichlorohydrin catalyzed by titanium silicate (TS-1) molecular sieve and hydrogen peroxide

摘要

In a mixed solvent system of acetonitrile and methanol,titanium silicate molecular sieve,TS-1,having MFI topology,efficiently catalyses the epoxidation of allyl chloride to the corresponding epichlorohydrin in excellent yields using dilute hydrogen peroxide (45%) as an oxidizing agent.