D-Glucose hydrogenation/hydrogenolysis reactions on noble metal (Ru, Pt)/activated carbon supported catalysts

摘要

In the present work we studied the hydrogenation/hydrogenolysis of D-glucose over Pt and Ru catalysts supported on activated micro/mesoporous carbon (AC), under low hydrogen pressure (1.6 MPa) and relatively high reaction temperature, i.e. 180 degrees C. We also studied the effect of metal content (1-5 wt.%), method of metal pre-treatment/reduction (H-2 at 350 degrees C or NaBH4) and reaction time (1-12 h). All the Ru and Pt/AC catalysts were very active (conversion >= 97%) with the Pt/AC catalysts being also very selective toward sorbitol (sel. >= 90%) irrespective of metal content, method of reduction and reaction time (up to 12 h). On the other hand, the Ru/AC catalysts exhibited a wide range of sorbitol selectivity values (55-93%) having various C-3-C-6 sugar alcohols (1,2,5,6-hexanetetrol, arabinitol, threitol, glycerol and 1,2-propanediol) as main by-products. The formation of by-products was dependent on the crystalline/amorphous nature of Ru and Ru(O)(chi)(delta 1) nanoparticles which were in turn affected by the Ru content and the method of reduction. (C) 2014 Elsevier B.V. All rights reserved.