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ANODIC DISSOLUTION OF THE FACES OF A MONOCRYSTAL OF COPPER IN CHLORIDE-CONTAINING AQUEOUS MEDIA

机译:含氯水介质中铜单晶表面的阳极溶解

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摘要

In the process of deformation of metals, parallel with changes in the sizes and shapes of the grains, we observe the rotation of the crystallographic axes in the three-dimensional space and their orientation in the same direction This leads to the formation of a texture whose influence on the chemical activity of the metal is significant in view the nonidentical configurations of the bonds of the surface atoms on different crystallographic faces [1]. As a result, the rates of anodic dissolution of these faces in aqueous solutions are different. At present, this process is most often modeled by using the cluster description of the metal surface and numerical methods of quantum chemistry [2].
机译:在金属变形的过程中,与晶粒尺寸和形状的变化平行,我们观察到晶体轴在三维空间中的旋转以及它们在相同方向上的取向。这导致了纹理的形成。考虑到不同晶体表面上表面原子键的不同构型,对金属化学活性的影响很大[1]。结果,这些面在水溶液中的阳极溶解速率不同。目前,这个过程通常是通过使用金属表面的簇描述和量子化学的数值方法来建模的[2]。

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