A New Set of Gas/Water Partition Coefficients for the Chloromethanes

摘要

In the literature,there is a considerable number of articles and reviews providing data and information on the solubility of chloromethanes in water.However,the substantial difference between the numerical values given by various authors hinders their practical application.In the current work we present the harmonized results of experimentally determined gas/water partition coefficients of CH_2C1_2,CHC1_3,and CCl_4,in the temperature range from 278 to 343 K,and with on uncertainty limit of less than 10%.