Biomimetic Alkene Epoxidation and Alkane Hydroxylation with Sodium Periodate Catalyzed by Mn(III)-salen Supported on Amberlite IRA-200

摘要

The Mn(III)-salen,containing phosphonium groups at the 5,5'-positions of the salen ligand supported on Amberlite IRA-200 via electrostatic binding was used for the oxidation of alkenes and alkanes with sodium periodate at room temperature in the presence of imidazoles as axial ligands,and the effect of solvent,different axial ligands,and various oxygen donors was investigated.This heteroge-nized catalyst shows high catalytic activity in alkene epoxidation and alkane hydroxylation.It showed high selectivity in the epoxidation of stilbenes,alpha-pinene,and (R)-(+)-limo-nene,and exhibits a particular ability to epoxidize linear alkenes.The stability and reusability of this new heteroge-nized metallo-salen complex was also investigated.The catalyst was characterized by FTIR,UV-Vis,SEM,and thermal analysis.