Zinc-Promoted Reduction of 1,2-Diketones: A Simple, Efficient, and Mild Approach to #alpha#-Hydroxy Ketones

Rahim Hekmatshoar; Majid M. Heravi; Yahya S. Beheshtiha; Farnoosh Faridbod

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Zinc-Promoted Reduction of 1,2-Diketones: A Simple, Efficient, and Mild Approach to #alpha#-Hydroxy Ketones

机译：锌促进的1,2-二酮的还原：＃alpha＃-羟基酮的简单，有效和温和的方法

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摘要

1,2-Diketones were readily converted to #alpha#-hydroxy ketones in high to excellent yields using zinc in saturated ammonium chloride solution.

机译：在饱和氯化铵溶液中使用锌，可以很容易地将1，2-二酮高产率地转化为＃α＃-羟基酮。

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来源
《Monatshefte fur Chemie》 |2002年第2期|共3页
作者
Rahim Hekmatshoar; Majid M. Heravi; Yahya S. Beheshtiha; Farnoosh Faridbod;
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正文语种 eng
中图分类化学;
关键词
Zinc; 1; 2-Diketones; alpha; -Hydroxy ketones;

机译：锌;1;2-二酮;α;-羟基酮;

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1. Zinc-Promoted Reduction of 1,2-Diketones: A Simple, Efficient, and Mild Approach to #alpha#-Hydroxy Ketones [J] . Rahim Hekmatshoar, Majid M. Heravi, Yahya S. Beheshtiha, Monatshefte fur Chemie . 2002,第2期

机译：锌促进的1,2-二酮的还原：＃alpha＃-羟基酮的简单，有效和温和的方法
2. Regioselective Copper-Catalyzed Oxidative Cross-Coupling of Imidazo[1,2-a] pyridines with Methyl Ketones: An Efficient Route for Synthesis of 1,2-Diketones [J] . Lei Sai, Chen GuiJun, Mai Yingying, Advanced synthesis & catalysis . 2016,第1期

机译：咪唑并[1,2-a]吡啶与甲基酮的区域选择性铜催化氧化交叉偶联：合成1,2-二酮的有效途径
3. Magnetic Supported Copper Nanoparticles: An Efficient Heterogeneous Catalyst for the Synthesis of 1,2-Diketones by Cross-Coupling Reaction of Imidazo[1,2-a]pyridines with Methyl Ketones [J] . Liu Yi, Zhan Haiying, Yao Kefan, European journal of organic chemistry . 2016,第29期

机译：磁性负载的铜纳米粒子：咪唑并[1,2-a]吡啶与甲基酮的交叉偶联反应合成1,2-二酮的高效多相催化剂
4. A mild and efficient approach for the reduction of graphene oxide [C] . Yufeng Wang, Chunhua Han, Bao Liu, International Conference on Advances in Materials and Manufacturing . 2013

机译：一种温和而有效的石墨烯氧化物的方法
5. Studies in the synthesis of bridged nitrogen heterocycles. I. Regioselectivity and stereoselectivity of Diels-Alder cycloadditions of 1,2-dihydropyridines with styrene and methyl vinyl ketone. II. A rapid and efficient synthetic route toward 5-substituted-2-azabicyclo[2.1.1]hexanes . [D] . Huang, Qiuli. 2004

机译：桥接氮杂环的合成研究。 I.1，2-二氢吡啶与苯乙烯和甲基乙烯基酮的Diels-Alder环加成反应的区域选择性和立体选择性。二。一种快速高效的合成方法，可替代5个取代的2-氮杂双环[2.1.1]己烷。
6. Desymmetrization of cyclic 13-diketones via Ir-catalyzed hydrogenation: an efficient approach to cyclic hydroxy ketones with a chiral quaternary carbon [O] . Quan Gong, Jialin Wen, Xumu Zhang 2019

机译：环状的13-二酮通过Ir催化的加氢脱对称：一种有效的方法与手性季碳的环状羟基酮
7. Desymmetrization of cyclic 1,3-diketones via Ir-catalyzed hydrogenation: an efficient approach to cyclic hydroxy ketones with a chiral quaternary carbon [O] . Quan Gong, Jialin Wen, Xumu Zhang 2019

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8. Chiral Synthesis via Organoboranes. 15. Selective Reductions. 42. Asymmetric Reduction of Representative Prochiral Ketones with Potassium 9-O-(1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranosyl)-9- boratabicyclo(3.3.1)-nonane [R] . Brown, H. C., Cho, B. T., Park, W. S. 1988

机译：有机硼烷的手性合成。 15.选择性减少。 42.用9-O-（1,2：5,6-二-O-异亚丙基-α-D-葡呋喃糖基）-9-硼三环（3.3.1） - 壬烷钾不对称还原代表性前手性酮

Zinc-Promoted Reduction of 1,2-Diketones: A Simple, Efficient, and Mild Approach to #alpha#-Hydroxy Ketones

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