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Chemical composition of the essential oil from Corsican Mentha aquatica - Combined analysis by GC(RI), GC-MS and ~(13)C NMR spectroscopy

机译:来自科西嘉薄荷的水的化学成分-通过GC(RI),GC-MS和〜(13)C NMR光谱进行组合分析

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摘要

The essential oil (EO) of M. aquatica L. growing wild in Corsica was isolated by dry vapor distillation and submitted to combined analysis by column chromatography over silica gel, GC(RI), GC-MS and ~(13)C NMR spectroscopy. The composition was dominated by oxygenated monoterpenes and characterized by the occurrence of menthofuran (50.7%) as the major component. In parallel, seven laboratory-distilled oil samples isolated from individual plants collected in Corsica were analyzed by GC(RI) and ~(13)C NMR spectroscopy. Only quantitative differences were observed between the samples. Beside the usual terpenes, various p-menthane lactones (mintlactone, isomintlactone, hydroxymintlactone, menthofurolactone and epimenthofurolactone) have been identified in all the oil samples.
机译:通过干蒸气蒸馏分离出在科西嘉岛野生的水产曼陀螺的精油(EO),并通过硅胶柱色谱,GC(RI),GC-MS和〜(13)C NMR光谱进行组合分析。该组合物以含氧的单萜为主要成分,其特征在于以薄荷醇(50.7%)为主要成分。同时,通过GC(RI)和〜(13)C NMR光谱分析了从科西嘉岛收集的各个植物中分离出的七个实验室蒸馏油样品。样品之间仅观察到定量差异。除了普通的萜烯外,在所有油样中还发现了各种对薄荷烷内酯(薄荷内酯,异薄荷内酯,羟基薄荷内酯,薄荷脑内酯和薄荷脑内酯)。

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