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The surface modification of CdSe-TGA quantum dots with multidentate biopolymer ligand based on salep: An easy route for enhancing fluorescence intensity

机译:基于salep的多齿生物聚合物配体对CdSe-TGA量子点的表面修饰:增强荧光强度的简便途径

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摘要

The optical properties of CdSe quantum dots (QDs) capped by thioglycolic acid (TGA) before and after surface modification with poly (acrylic acid) grafted onto salep (salep-g-PAA), as a biopolymer-based multidentate ligand, were examined. The results showed that the fluorescence intensity as well as the stability of CdSe QDs was incredibly increased after surface modification with the biopolymer-based ligand. To provide more evidence for the occurrence of surface modification, the prepared CdSe-salep-g-PAA QDs were characterized by thermo-gravimetric analysis (TG), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR).
机译:在以生物聚合物为基的多齿配体接枝到Salep(salep-g-PAA)上的聚丙烯酸改性表面之前和之后,研究了巯基乙酸(TGA)封端的CdSe量子点(QDs)的光学性质。结果表明,用基于生物聚合物的配体对表面进行修饰后,CdSe QDs的荧光强度和稳定性得到了显着提高。为了提供更多的表面改性证据,通过热重分析(TG),透射电子显微镜(TEM),扫描电子显微镜(SEM)和傅里叶变换红外光谱对制备的CdSe-salep-g-PAA量子点进行了表征。 (FT-IR)。

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