The preparation of an elastomer/silicate layer nanocompound with an exfoliated structure and a strong ionic interfacial interaction by utilizing an elastomer latex containing pyridine groups

摘要

A great variety of polymer/layered silicate (PLS) nanocomposites have been reported, however, there are few exfoliated PLS nanocomposites and their inorganic–organic interfaces are still a great problem, especially for the elastomers. In this research, a kind of exfoliated elastomer/silicate layer nanocompound was prepared and proved by XRD and TEM, in which 10 phr Na+-montmorillonite was dispersed in butadiene–styrene–vinyl pyridine rubber by latex compounding method with acidic flocculants. Moreover, a dynamic mechanical thermal analyzer (DMTA) suggested a strong interfacial interaction (interaction parameter BH = 4.91) between the silicate layers and macromolecules in addition to the weak inorganic–organic interfacial interaction, and solid state 15N NMR indicated the formation of a strong ionic interface through the acidifying pyridine. Subsequently, a remarkable improvement of the dispersing morphology, mechanical performance and gas barrier property appeared, compared to that using calcium ion flocculants. This supports the formation of an exfoliated structure and an improved interfacial interaction.