Preparation and Characterization of Poly(ethyl hydrazide)-Grafted Oil Palm Empty Fruit Bunch Fibre for the Removal of Cu(II) Ions from an Aqueous Environment

摘要

Poly(ethyl hydrazide)-grafted oil palm empty fruit bunch fibre (peh-g-opefb) was successfully prepared by heating poly(methyl acrylate)-grafted opefb (pma-g-opefb) at 60 °C for 4 h with a solution of hydrazine hydrate (15% v/v) in ethanol. The Fourier transform infrared spectrum of the product shows a secondary amine peak at 3267 cm~(-1), with amide carbonyl peaks at 1729 cm~(-1) and 1643 cm~(-1). The chelating ability of peh-g-opefb was tested with copper ion in aqueous solution. A batch adsorption study revealed that maximum adsorption of copper ion was achieved at pH 5. An isotherm study showed the adsorption follows a Langmuir model, with a maximum adsorption capacity of 43.48 mg g~(-1) at 25 °C. A kinetic study showed that the adsorption of copper ion rapidly reaches equilibrium and follows a pseudo–second-order kinetic model, with a constant rate of 7.02 × 10~(-4) g mg~(-1) min~(-1) at 25 °C. The Gibbs free energy, ΔG~0, value is negative, indicating a spontaneous sorption process. Entropy, ΔS~0, gives a positive value, indicating that the system is becoming increasingly disordered after the adsorption of copper ion. A positive enthalpy value, ΔH~0, shows that the endothermic process takes place during the adsorption and is more favourable at high temperatures.