L-Proline Catalyzed Michael Additions of Thiophenols to alpha, beta-Unsaturated Compounds,Particularly alpha-Enones,in the Ionic Liquid[bmim]PF_6

Peter Kotrusz; Stefan Toma

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L-Proline Catalyzed Michael Additions of Thiophenols to alpha, beta-Unsaturated Compounds,Particularly alpha-Enones,in the Ionic Liquid[bmim]PF_6

机译：L-脯氨酸在离子液体[bmim] PF_6中催化了硫酚与α，β-不饱和化合物，特别是α-烯酮的迈克尔加成反应

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摘要

L-Proline catalyzed additions of 13 different thiols to 11 different alpha-enone Michael acceptors in[bmim]PF_6 are reported.Reasonable to high yields of the reaction products were isolated in most cases.

机译：据报道，在[bmim] PF_6中，L-脯氨酸催化了11种不同的硫醇向11种不同的α-烯酮迈克尔受体的加成反应。在大多数情况下，可分离出高产率的反应产物。

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《Molecules》 |2006年第3期|共9页
作者
Peter Kotrusz; Stefan Toma;
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正文语种 eng
中图分类有机化学;
关键词
Thiols; Enones; Michael; Addition; Organocatalysis; Ionic Liquids;

机译：硫醇;烯酮;迈克尔;加成;有机催化;离子液体;

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专利

1. L-Proline Catalyzed Michael Additions of Thiophenols to alpha, beta-Unsaturated Compounds,Particularly alpha-Enones,in the Ionic Liquid[bmim]PF_6 [J] . Peter Kotrusz, Stefan Toma Molecules . 2006,第2a3期

机译：L-脯氨酸在离子液体[bmim] PF_6中催化了硫酚与α，β-不饱和化合物，特别是α-烯酮的迈克尔加成反应
2. A fast and highly efficient protocol for Michael addition of N-heterocycles to alpha,beta-unsaturated compound using basic ionic liquid [bmIm]OH as catalyst and green solvent [J] . Xu JM, Qian C, Liu BK, Tetrahedron . 2007,第4期

机译：使用碱性离子液体[bmIm] OH作为催化剂和绿色溶剂，快速高效地将N杂环迈克尔加成至α，β-不饱和化合物的方案
3. Thio-Michael addition of alpha,beta-unsaturated amides catalyzed by Nmm-based ionic liquids [J] . Liu Yawei, Lai Zhenzhen, Yang Pengkun, RSC Advances . 2017,第68期

机译：硫代麦酰胺加入α，β-不饱和酰胺催化的NMM基离子液体催化
4. Li_2SO_4-Li_2O-P_2O_5 Ionic Glass Dispersed with Bmim PF_6 Ionic Liquid: Electrical Transport and Thermal Stability Investigations [C] . Munesh Rathore, Anshuman Dalvi, Anil Kumar DAE Solid State Physics Symposium . 2014

机译：Li_2SO_4-Li_2O-P_2O_5离子玻璃分散有BMIM PF_6离子液体：电气运输和热稳定性研究
5. Molecular Design for a Novel Organotin Hydride and Ferric Chloride Mediated Michael Addition of Dicarboxylic Acid Esters to alpha,beta-Unsaturated Ketones. [D] . Deka, Dibakar Chandra. 2010

机译：新型有机锡氢化物和氯化铁介导的二羧酸酯向α，β-不饱和酮的迈克尔加成反应的分子设计。
6. L-Proline Catalyzed Michael Additions of Thiophenols to αβ-Unsaturated Compounds Particularly α-Enones in the Ionic Liquid bmimPF6 [O] . Peter Kotrusz, Štefan Toma 2006

机译：L-脯氨酸在离子液体bmim PF6中催化硫酚与αβ-不饱和化合物（特别是α-烯酮）的迈克尔加成反应
7. L-Proline Catalyzed Michael Additions of Thiophenols to ÃŽÂ±,ÃŽÂ²-Unsaturated Compounds, Particularly ÃŽÂ±-Enones, in the Ionic Liquid [bmim]PF6 [O] . Stefan Toma, Peter Kotrusz 2006

机译：L-脯氨酸催化硫醇在离子液体[bmim] PF6中的Michael 、,、Ž-不饱和化合物，尤其是-烯酮的迈克尔加成反应

L-Proline Catalyzed Michael Additions of Thiophenols to alpha, beta-Unsaturated Compounds,Particularly alpha-Enones,in the Ionic Liquid[bmim]PF_6

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