Stereoselective chlorothiolation of artemisinin-derived C-10 oxa terminal alkynes

Surineni Naresh; Buragohain Pori; Barua Nabin C.

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Stereoselective chlorothiolation of artemisinin-derived C-10 oxa terminal alkynes

机译：青蒿素衍生的C-10氧杂末端炔的立体选择性氯硫醇化

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A mild and efficient strategy is explored on the highly sensitive artemisinin-derived C-10 oxa terminal alkynes. Several novel artemisinin-derived (E)-2-chloroalkenyl sulfides (20) have been synthesized by using this protocol to study their anticancer activities.

机译：在高度敏感的青蒿素衍生的C-10 oxa末端炔烃上探索了一种温和而有效的策略。通过使用该方案研究了几种新颖的青蒿素衍生的（E）-2-氯烯基硫醚（20），以研究其抗癌活性。

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《Molecular diversity》 |2015年第4期|共8页
作者
Surineni Naresh; Buragohain Pori; Barua Nabin C.;
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正文语种 eng
中图分类分子物理学、原子物理学;
关键词
Artemisinin; Chlorothiolation; Alkynes; Vinyl sulfides;

机译：青蒿素;氯硫代;炔烃;乙烯基硫化物;

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1. Stereoselective chlorothiolation of artemisinin-derived C-10 oxa terminal alkynes [J] . Surineni Naresh, Buragohain Pori, Barua Nabin C. Molecular diversity . 2015,第4期

机译：青蒿素衍生的C-10氧杂末端炔的立体选择性氯硫醇化
2. Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling of Oxa- and Azabicyclic Alkenes with Enones and Electron-Rich Alkynes [J] . Subramaniyan Mannathan, Chien-Hong Cheng Advanced synthesis & catalysis . 2014,第10期

机译：镍催化的氧杂和氮杂双烯烃与烯酮和富电子炔烃的区域和立体选择性还原偶联
3. Stereoselective [2+2+2] cocyclotrimerization of oxa- and azabenzonorbornadienes with alkynes catalyzed by nickel complexes: first transition metal-mediated synthesis of isobenzofuran and isoindole precursors [J] . Sambaiah T., Cheng CH., Huang DJ. Journal of the Chemical Society, Perkin Transactions 1 . 2000,第2期

机译：镍配合物催化的氧杂-和氮杂-苯并氮杂降冰片二烯与炔烃的立体选择性[2 + 2 + 2]共环三聚：过渡金属介导的异苯并呋喃和异吲哚前体的合成
4. Construction of Carbon Skeletons by Transition Metal-Catalyzed Regio- and Stereoselective Addition of Carbon-Chalcogen Bonds to Alkynes and Allenes [C] . Masashi Tovofuku, Erika Murase, Atsushi Okada Symposium on Organometallic Chemistry . 2008

机译：通过过渡金属催化的碳骨架施工碳骨架和立体选择性加入碳 - 硫醇键与炔烃和艾伦
5. I. Total synthesis, stereochemical reassignment, and biological evaluation of (+)-neopeltolide and related stereoisomers. II. Development of chiral benzylsilanes: Reagents for stereoselective, silicon-mediated oxa-Pictet-Spengler reactions. [D] . Youngsaye, Willmen Wing-Menn. 2010

机译：I.（+）-neopeltolide和相关立体异构体的全合成，立体化学重新分配和生物学评估。二。手性苄基硅烷的开发：用于立体选择性硅介导的oxa-Pictet-Spengler反应的试剂。
6. Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions [O] . Dat Phuc Tran, Yuki Sato, Yuki Yamamoto, 2021

机译：基于自由基条件下具有四苯基二膦膦酮的高度测定和立体选择性膦酰磷化酯
7. Cover Picture: Palladium-Catalyzed Regio- and Stereoselective Chlorothiolation of Terminal Alkynes with Sulfenyl Chlorides (Chem. Asian J. 1/2014) [O] . Masayuki Iwasaki, Tomoya Fujii, Arisa Yamamoto, 2013

机译：封面图片：钯催化的亚炔醇末端和立体选择性含氟化含量亚砜氯化物（Chem。亚洲亚洲J.1 / 2014）

Stereoselective chlorothiolation of artemisinin-derived C-10 oxa terminal alkynes

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