Reactions of 5-aryl-3-arylmethylene substituted 3H-furan-2-ones and 3H-pyrrol-2-ones with acetoacetic ester

Aniskova TV; Yegorova AY; Chadina VV

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Reactions of 5-aryl-3-arylmethylene substituted 3H-furan-2-ones and 3H-pyrrol-2-ones with acetoacetic ester

机译：5-芳基-3-芳基亚甲基取代的3H-呋喃-2-酮和3H-吡咯-2-酮与乙酰乙酸的反应

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The title reactions afforded ethyl 4-(arylmethylene)-6-oxo-2-aryl-4,5,6,7-tetrahydrobenzofuran-5-carboxylates and ethyl 4-(arylmethylene)-6-oxo-2-aryl-4,5,6,7-tetrahydro-1H-indole-5-carboxylates the structures of which were confirmed by IR and H-1 NMR spectroscopy.

机译：标题反应得到乙基4-（芳基亚甲基）-6-氧代-2-芳基-4,5,6,7-四氢苯并呋喃-5-羧酸酯和乙基4-（芳基亚甲基）-6-氧代-2-芳基-4， 5,6,7-四氢-1H-吲哚-5-羧酸酯的结构已通过IR和H-1 NMR光谱证实。

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《Mendeleev Communications 》 |2008年第3期| 共2页
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Aniskova TV; Yegorova AY; Chadina VV;
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1. Reactions of 5-aryl-3-arylmethylene substituted 3H-furan-2-ones and 3H-pyrrol-2-ones with acetoacetic ester [J] . Aniskova TV, Yegorova AY, Chadina VV Mendeleev Communications . 2008 ,第3期

机译：5-芳基-3-芳基亚甲基取代的3H-呋喃-2-酮和3H-吡咯-2-酮与乙酰乙酸的反应
2. Cascade S(N)2 '-SNAr, Elimination, and 1,5-Hydride Shift Reactions by Acetylacetone/Acetoacetic Esters: Synthesis of 9,10-Dihydroacridines [J] . Gupta Tanu, Bharadwaj Kishor Chandra, Singh Radhey M. European journal of organic chemistry . 2016 ,第29期

机译：乙酰丙酮/乙酰乙酸酯的级联S（N）2'-SNAr，消除和1,5-氢化物转移反应：9,10-二氢ac啶的合成
3. Efficient one-pot synthesis of functionalized piperidine scaffolds via ZrOCl2·8H2O catalyzed tandem reactions of aromatic aldehydes with amines and acetoacetic esters [J] . Sarita Mishra, Rina Ghosh Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2011 ,第22期

机译：通过ZrOCl2·8H2O催化的芳族醛与胺和乙酰乙酸酯的串联反应有效地一锅法合成官能化哌啶骨架
4. Conjugate Substitution of α-(Halomethyl)acrylate: A Facile, Versatile, and Convenient Reaction for Poly (conjugated ester) Synthesis [C] . Yasuhiro Kohsaka, Keito Hagiwara, Takumi Miyazaki 日本化学会春季年会講演予稿集 . 2018

机译：α-（卤代甲基）丙烯酸酯的共轭取代：适用，通用，方便的聚（共轭酯）合成反应
5. Catalytic enantioselective synthesis of O-and N-substituted quaternary carbon stereogenic centers: 1. Aluminum-catalyzed alkylations of alpha-ketoesters with dialkylzinc reagents. 2. Silver-catalyzed vinylogous Mannich-type reactions of alpha-ketoimine esters with siloxyfurans [D] . Wieland, Laura Caroline 2008

机译：O和N取代的季碳立构中心的催化对映选择性合成：1.用二烷基锌试剂进行铝催化的α-酮酸酯的烷基化。 2.α-酮亚胺酯与甲硅烷氧基呋喃的银催化乙烯基曼尼希型反应
6. Influence of Sulfur for Oxygen Substitution in the Solvolytic Reactions of Chloroformate Esters and Related Compounds [O] . Malcolm J. D’Souza, Dennis N. Kevill 1997

机译：硫在氯甲酸酯和相关化合物的溶剂分解反应中对氧取代的影响
7. Syntheses of arenediacetic esters and acetonyl-substituted arylacetic esters by means of Friedel-Crafts reaction with .ALPHA.-acyl-.ALPHA.-chlorosulfides. [O] . HIROYUKI ISHIBASHI, MASAZUMI IKEDA, HONGDAE CHOI, 1985

机译：通过与α-酰基-α-氯硫醚的Friedel-Crafts反应的Friedel-Crafts反应合成芳基酯酯和乙酰醇 - 取代的芳基乙酸酯.-氯硫化物。

Reactions of 5-aryl-3-arylmethylene substituted 3H-furan-2-ones and 3H-pyrrol-2-ones with acetoacetic ester

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