Synthesis and molecular structure of a chiral ferrocenylphosphine

Karasik AA; Spiridonova YS; Yakhvarov DG; Sinyashin OG; Lonnecke P; Sommer R; Hey-Hawkins E

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Synthesis and molecular structure of a chiral ferrocenylphosphine

机译：手性二茂铁基膦的合成及分子结构

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摘要

The first chiral (aminomethyl)ferrocenylphosphine (S,S)-1,5-bis(alpha-methylbenzyl)-3,7-bisferrocenyl-1,5-diaza-3,7-diphosphacyclooctane was obtained via a condensation reaction of bis(hydroxymethyl)ferrocenylphosphine with chiral (S)-alpha-methylbenzylamine.

机译：第一手性（氨基甲基）二茂铁基膦（S，S）-1,5-双（α-甲基苄基）-3,7-双二茂铁基-1,5-二氮杂-3,7-二磷环辛烷是通过双（羟基甲基）二茂铁基膦与手性（S）-α-甲基苄胺。

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来源
《Mendeleev Communications》 |2005年第3期|共2页
作者
Karasik AA; Spiridonova YS; Yakhvarov DG; Sinyashin OG; Lonnecke P; Sommer R; Hey-Hawkins E;
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正文语种 eng
中图分类化学;
关键词
(ETA(5)-C5H5)FE(ETA(5)-C5H4); HYDROXYMETHYLPHOSPHINES; DERIVATIVES; COMPLEXES; CATALYSTS; FC;

机译：（ETA（5）-C5H5）FE（ETA（5）-C5H4）;羟基甲基膦;衍生物;络合物;催化剂;FC;

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专利

1. Synthesis and molecular structure of a chiral ferrocenylphosphine [J] . Karasik AA, Spiridonova YS, Yakhvarov DG, Mendeleev Communications . 2005,第3期

机译：手性二茂铁基膦的合成及分子结构
2. Synthesis, Solid-State Structures, and Molecular Recognition of Chiral Molecular Tweezer and Related Structures Based on a Rigid Bis-Naphthalene Cleft [J] . He Zhenfeng, Yang Xin, Jiang Wei Organic letters . 2015,第15期

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5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Synthesis Crystal Structure of a New Triosmium Alkylidyne Carbonyl Cluster Containing a Chiral Ferrocenylphosphine Ligand [O] . Wai-Yeung Wong 2005

机译：含手性二茂铁基膦配体的新Tri烷基炔基羰基簇的合成晶体结构
7. Synthesis and Crystal Structure of a New Triosmium Alkylidyne Carbonyl Cluster Containing a Chiral Ferrocenylphosphine Ligand [O] . Wai-Yeung Wong 2005

机译：含手性二茂铁基膦配体的新Tri烷基炔基羰基簇的合成与晶体结构
8. Synthesis of a Chiral Non-Racemic Segmented Screw-Like Oligomer. An Unusual Formof Molecular Chirality [R] . Bedworth, P. V., Tour, J. M. 1994

机译：手性非外消旋链段螺旋状低聚物的合成。一种不寻常的分子手性形式

Synthesis and molecular structure of a chiral ferrocenylphosphine

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