Hydrothermal synthesis, crystal structure and magnetic properties of a new 3D Mn-II complex based on the flexible ligand 5-(4-pyridyl)methoxyisophthalic acid

摘要

A new 3D coordination polymer [Mn2L2(H2O)(2)center dot 2DMF center dot 2H(2)O](n) [H2L = 5-(4-pyridyl)methoxyisophthalic acid] with a {4(2).6}(2){4(4).6(2).8(7).10(2)} net has been synthesized from H2L by a hydrothermal method. Magnetic susceptibility measurements indicated antiferromagnetic interaction between the adjacent Mn-II ions in the polymer.