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Particle size, size distribution and morphological evaluation of glass fiber reinforced plastic (GRP) industrial by-product

机译:玻璃纤维增​​强塑料(GRP)工业副产物的粒度,粒度分布和形态评估

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摘要

The waste management of glass fiber reinforced polymer (GRP) materials, in particular those made with thermosetting resins, is a critical issue for the composites industry because these materials cannot be reprocessed. Therefore, most thermosetting GRP waste is presently sent to landfill, in spite of the significant environmental impact caused by their disposal in this way. The limited GRP waste recycling worldwide is mostly due to its intrinsic thermosetting properties, lack of characterization data and unavailability of viable recycling and recovery routes. One of the possibility for re-using GRP industrial by-product is in form of powder as a partial aggregate replacement or filler addition in cement based composites for applications in sustainable construction materials and technologies. However, the feasibility of this kind of reutilization strongly depends on the morphology and particle size distribution of a powder made up of polymer granules and glass fibers. In the present study, the use of image analysis method, based on scanning electron microscopy (SEM) and ImageJ processing program, is proposed in order to evaluate the morphology of the particles and measure the particle size and size distribution of fine GRP waste powder. The obtained results show a great potential of such a method in order to be considered as a standardized method of measurement and analysis in order to characterize the grain size and size distribution of GRP particles before exploiting any compatibility issue for its recycling management.
机译:玻璃纤维增​​强聚合物(GRP)材料(尤其是由热固性树脂制成的材料)的废物管理对于复合材料行业来说是一个关键问题,因为这些材料无法进行再加工。因此,尽管以这种方式进行处置会对环境造成重大影响,但目前大多数热固性GRP废物仍被送至垃圾填埋场。全球范围内有限的GRP废物回收主要是由于其固有的热固性,缺乏特征数据以及缺乏可行的回收和回收途径。重复使用GRP工业副产品的可能性之一是粉末形式,可作为部分骨料的替代品或在水泥基复合材料中添加填料,用于可持续建筑材料和技术。但是,这种再利用的可行性在很大程度上取决于由聚合物颗粒和玻璃纤维组成的粉末的形态和粒径分布。在本研究中,提出了使用基于扫描电子显微镜(SEM)和ImageJ处理程序的图像分析方法来评估颗粒的形态,并测量GRP细粉的粒度和粒度分布。所获得的结果表明,这种方法具有巨大的潜力,可以被认为是一种标准化的测量和分析方法,以便在利用任何相容性问题进行回收管理之前表征GRP颗粒的晶粒尺寸和尺寸分布。

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