The mystery of mercury-layers on ancient coins - A multianalytical study on the Sasanian coins under the Reign of Khusro II

摘要

40 Sasanian silver coins of the emperor Khusro II (591-628) belonging to the Coin Collection of the Kunsthistorisches Museum Vienna (KHM) as well as 188 coins of the same emperor acquired at the free coin market were analyzed using micro-X-ray fluorescence analysis (mu-XRF) in the course of the research project "Sylloge Nummorum Sasanidarum". These studies revealed the presence of mercury in the XRF spectra of a bigger part of the coins. First investigations with complementary techniques showed that the mercury is present as a surface layer. Therefore, further detailed studies were performed on polished sections using the Particle Induced X-ray Emission technique with a proton microprobe (mu-PIXE) that offers quantitative and spatially resolved elemental information with micron resolution, scanning micro-X-ray fluorescence (mu-XRF) analyses for a better understanding of the elemental distribution on the surface and polished sections of the coins and finally confocal micro-XRF (3D mu-XRF or CMXRF) analyses for revealing information on the surface layering and elemental in-depth distribution. The synergistic application of these methods offered detailed and improved information on the structure of the mercury-layer on the surface of the silver coins supporting assumptions dating back to 1976/78 indicating medical treatments using Hg as basis for this phenomenon. (C) 2015 Elsevier B.V. All rights reserved.