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Evolution of corrosion protection performance of hybrid silica based sol-gel nanocoatings by doping inorganic inhibitor

机译:掺杂无机抑制剂对二氧化硅杂化溶胶-凝胶纳米涂层防腐性能的影响

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摘要

Silica based hybrid sol-gel coatings were developed to protect AA2024 alloy from corrosion. In order to have an active protection, cerium nitrate corrosion inhibitor was introduced into the coating system. The anti-corrosion properties of the coatings were evaluated by electrochemical impedance spectroscopy (EIS) and potentiodynamic scanning (PDS) methods. The structure of the films was studied by scanning electron microscopy (SEM) after corrosion. The results indicate that the improvement of the protection properties of the films occurred with immersion time. This would imply that cerium ions could reach the defects, hindering the corrosion reactions and thus reduces the corrosion rate.
机译:开发了基于二氧化硅的混合溶胶-凝胶涂料,以保护AA2024合金免受腐蚀。为了获得主动保护,将硝酸铈腐蚀抑制剂引入了涂料体系。通过电化学阻抗谱(EIS)和电位动力学扫描(PDS)方法评估了涂层的防腐性能。腐蚀后通过扫描电子显微镜(SEM)研究了膜的结构。结果表明,随着浸没时间的增加,薄膜的保护性能得到改善。这将暗示铈离子可能到达缺陷,从而阻碍腐蚀反应,从而降低腐蚀速率。

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