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Hydrogen permeation measurements in natural sea environment

机译:天然海洋环境中的氢渗透测量

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The specially designed, fully equipped, and computerized devices for the underwater long-term measurements have been used to study the hydrogen permeation rate through the structural steels under natural sea water conditions. By applying constant cathodic potentials, the polarization current and the hydrogen permeation rate were recorded. The temperature and the concentration of S{sup}(-2) ions in sea water were also measured. After the tests, the concentration of residual hydrogen in samples and the chemistry of the membrane surface were analyzed. The obtained permeation data were compared with the S{sup}(-2) content in sea water and with the chemistry and appearance of formed deposits. The effect of SRB on the hydrogen permeation through structural steels is dependent on the site of the sample placing and on the sea water temperature. At a lower water temperature, the low hydrogen absorption was measured due to a lower activity of SRB. The highest hydrogen uptake accompanied by the highest content of S in corrosion and cathodic deposits was observed for membranes situated on the sea bed. The electric field of cathodically protected wall did not affect the hydrogen absorption. The hydrogen uptake recorded under the natural sea conditions can be higher than that measured in the laboratory tests, which should be taken into account while servicing marine constructions, especially embedded ones.
机译:经过专门设计,设备齐全且计算机化的水下长期测量设备已用于研究天然海水条件下结构钢中的氢渗透速率。通过施加恒定的阴极电位,记录了极化电流和氢的渗透速率。还测量了海水中S {sup}(-2)离子的温度和浓度。测试后,分析样品中残留氢的浓度和膜表面的化学性质。将获得的渗透数据与海水中S {sup}(-2)的含量以及所形成沉积物的化学性质和外观进行比较。 SRB对氢通过结构钢渗透的影响取决于样品放置的位置和海水温度。在较低的水温下,由于SRB的活性较低,因此测得的氢吸收率较低。对于位于海床的膜,观察到了最高的氢吸收以及最高的S和腐蚀沉积物中的S含量。阴极保护壁的电场不影响氢吸收。在自然海况下记录的氢吸收量可能高于实验室测试中测得的氢吸收量,在维修海洋建筑(尤其是嵌入式建筑)时应予以考虑。

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