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Corrosion and biocompatibility of PPy/PEG coating electrodeposited on Ti_6Al_7Nb alloy

机译:电沉积在Ti_6Al_7Nb合金上的PPy / PEG涂层的腐蚀和生物相容性

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摘要

This work aims to improve the corrosion rate of Ti_6Al_7Nb alloy and to increase its biocompatibility at the same time, obtaining polymer composite films based on polypyrrole/polyethylene glycol (PPy/PEG). The elaboration method was electrodeposition. FT-IR analysis was performed in order to emphasize the formation of the PPy-PEG composite film by incorporating PEG into the polymer structure. The paper is focused on PEG (400 molecular weight) effect on the corrosion in bioliquids (as tested electrochemical bioliquid was chosen Hank's balanced salt solution) and on the biocompatibility properties. The PPy film significantly improves the biocompatibility of the Ti_6Al_7Nb alloy. The PEG presence in the polymerization solution leads to more stable composite polymer films on the titanium alloy surface with a better corrosion resistance and a more hydrophilic behaviour comparing with the PPy film. The increase of cell viability and proliferation potential as compared to the PPy film is not important.
机译:这项工作旨在提高Ti_6Al_7Nb合金的腐蚀速率并同时提高其生物相容性,从而获得基于聚吡咯/聚乙二醇(PPy / PEG)的聚合物复合膜。加工方法是电沉积。进行FT-IR分析以强调通过将PEG掺入聚合物结构中PPy-PEG复合膜的形成。本文重点关注PEG(400分子量)对生物液体中腐蚀的影响(如经测试的电化学生物液体被选为Hank的平衡盐溶液)和生物相容性。 PPy膜大大改善了Ti_6Al_7Nb合金的生物相容性。与PPy薄膜相比,聚合溶液中PEG的存在导致钛合金表面上的复合聚合物薄膜更稳定,具有更好的耐腐蚀性和更亲水的行为。与PPy膜相比,细胞活力和增殖潜能的增加并不重要。

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