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1,3-Bis-dibutylaminopropan-2-ol as inhibitor for reinforcement steel in chloride-contaminated simulated concrete pore solution

机译:1,3-双-二丁基氨基丙-2-醇作为氯化物污染的模拟混凝土孔隙溶液中钢筋的抑制剂

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摘要

An organic compound, 1,3-bis-dibutylaminopropan-2-ol (BDAP) was prepared and tested experimentally as inhibitor for reinforcement steel in simulated concrete pore solution. The electrochemical behavior of carbon steel electrodes immersed in simulated pore solutions with different concentration of BDAP was investigated by electrochemical measurements. Adsorption isotherm was determined based on the inhibition efficiency. The surface composition was evaluated via X-ray photoelectron spectroscopy (XPS) as well in order to verify the presence and adsorption property of BDAP. The results showed that BDAP could effectively suppress the anodic process of carbon steel corrosion and the inhibition efficiency was improving with the increase of inhibitor concentration. BDAP could adsorb on carbon steel surface according to Langmuir adsorption isotherm. XPS spectrum certified the existence of BDAP on the steel surface.
机译:制备了一种有机化合物1,3-双-二丁基氨基丙-2-醇(BDAP),并在模拟混凝土孔隙溶液中对作为钢筋抑制剂的实验进行了测试。通过电化学测量研究了碳钢电极在不同浓度BDAP的模拟孔溶液中的电化学行为。根据抑制效率确定吸附等温线。还通过X射线光电子能谱法(XPS)评估了表面组成,以验证BDAP的存在和吸附性能。结果表明,BDAP可有效抑制碳钢腐蚀的阳极过程,且随着缓蚀剂浓度的增加,缓蚀效率提高。 BDAP可以根据Langmuir吸附等温线吸附在碳钢表面。 XPS光谱证明了钢表面上存在BDAP。

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