Correlation diagrams of stereoisograms for characterizing uninuclear promolecules. A remedy for over-simplified dichotomy in stereochemical terminology

摘要

Correlation diagrams of stereoisograms for characterizing stereoisomers have been developed so as to provide more information on both geometric and stereoisomeric features than a separate use of a stereoisogram. They are capable of solving most problems which have been left unsolved within the traditional terminology of stereochemistry and related chemoinformatics practices, e.g., over-simplified features of the conventional dichotomy between enantiomers and diastereomers, incomplete separation of RS-stereogenicity from chirality, unconscious disregard of local RS-stereogenicity and confusion of it with local chirality, implications of reflection-invariant cases of the CIP priority system, and others.