Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone)

Ahmet Ince; Niyazi Bicak

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Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone)

机译：使用非乙烯基交联剂的乙烯基单体的交联共聚：吗啉取代的聚（乙烯基甲基酮）

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Summary: Morpholine substituted poly(vinyl methyl ketone) (MSP) is presented as non-vinyl crosslinker forming insoluble polymers in polymerization of vinyl monomers. In this process, crosslinking occurs via double bonds in situ formed by thermal de-amination of MSP above 70 ℃ as demonstrated in polymerization of methylmethacrylate (MMA), styrene and 4-vinyl pyridine (4-VP) monomers.

机译：摘要：吗啉取代的聚（乙烯基甲基酮）（MSP）作为乙烯基单体聚合中形成非乙烯基交联剂的不溶性聚合物而存在。在此过程中，交联反应是通过在70℃以上对MSP进行热脱氨作用而在原位形成的双键发生的，这在甲基丙烯酸甲酯（MMA），苯乙烯和4-乙烯基吡啶（4-VP）单体的聚合反应中得到了证明。

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《Macromolecular symposia》 |2015年第1期|共4页
作者
Ahmet Ince; Niyazi Bicak;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
conjugated polymers; crosslinking; gelation; reactive processing;

机译：共轭聚合物;交联;胶凝;反应加工;

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1. Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone) [J] . Ahmet Ince, Niyazi Bicak Macromolecular symposia . 2015,第1期

机译：使用非乙烯基交联剂的乙烯基单体的交联共聚：吗啉取代的聚（乙烯基甲基酮）
2. Synthesis of photo-scissible poly(p-hydroxystyrene) derivatives by radical copolymerization of p-hydroxystyrene derivatives and methyl vinyl ketone [J] . Ishikawa T., Morino K., Sudo A., Journal of Polymer Science, Part A. Polymer Chemistry . 2011,第21期

机译：对羟基苯乙烯衍生物与甲基乙烯基酮的自由基共聚合成可光剪切的聚对羟基苯乙烯衍生物
3. Functional modification of poly(vinyl alcohol) by copolymerizing with a hydrophobic cationic double alkyl-substituted monomer [J] . Ma Jiaojiao, Yin Xiande, Xiao Hongqin, Journal of Applied Polymer Science . 2016,第35a36期

机译：通过与疏水性阳离子双烷基取代单体共聚来对聚乙烯醇进行功能改性
4. Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone) [C] . Ahmet Ince, Niyazi Bicak Polymers and Organic Chemistry . 2015

机译：使用非乙烯基交联剂的乙烯基单体的交联共聚：吗啉取代聚（乙烯基甲基酮）
5. Conducting polymer blends: Polypyrrole and polythiophene blends with polystyrene, polycarbonate resin, poly(vinyl alcohol) and poly(vinyl methyl ketone). [D] . Wang, Hsing-Lin. 1992

机译：导电聚合物共混物：聚吡咯和聚噻吩与聚苯乙烯，聚碳酸酯树脂，聚乙烯醇和聚乙烯甲基酮的共混物。
6. Multifunctional Monomers based on Vinyl Sulfonates and Vinyl Sulfonamides for Crosslinking Thiol-Michael Polymerizations: Monomer Reactivity and Mechanical Behavior [O] . Jasmine Sinha, Maciej Podgórski, Sijia Huang, -1

机译：基于乙烯基磺酸盐和乙烯基磺酰胺的多功能单体用于交联硫醇-迈克尔聚合反应：单体反应性和机械行为
7. Structure-reactivity relations of conjugated and unconjugated monomers: acrylates and methyl vinyl ketone in copolymerization with styrene compared with vinyl esters in copolymerization with ethylene [O] . Schrijver, J, German, AL Anton = Ton 1983

机译：共轭和非共轭单体的结构反应关系：与苯乙烯共聚的丙烯酸酯和甲基乙烯基酮与与乙烯共聚的乙烯基酯相比
8. Nuclear Magnetic Resonance Studies of Ionomers. 5. Spectra of Poly(Methyl Methacrylate-co-4-Vinyl Pyridine), Poly(Methyl Methacrylate-co-2-Methyl-5-Vinyl Pyridine), and Their Quaternized Derivatives [R] . Natansohn, A., Eisenberg, A. 1987

机译：离子聚合物的核磁共振研究。 5.聚（甲基丙烯酸甲酯 - 共-4-乙烯基吡啶甲基），聚（甲基丙烯酸甲酯 - 共聚-2-甲基-5-乙烯基吡啶）及其季铵化衍生物的光谱

Crosslinking Copolymerization of Vinyl Monomers Using Non-Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone)

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