PREPARATION OF RUTHENIUM-CONTAINING POLYCARBONATE FILMS AND THE CHEMISTRY OF RUTHENIUM IN POLYCARBONATE

摘要

RuCl3 . 3H(2)O complexes have been incorporated into polycarbonate using solvent. The interactions between Ru complexes and polycarbonate (PC) are examined by infrared spectroscopy and thermal analysis. The reaction chemistries of these Ru-containing films have been investigated by reacting the Ru sites with CO, O-2, H-2, D-2, NO, and C2H4. They show interesting catalytic activities in various gas phase reactions under relatively mild conditions such as NO reduction, hydrogenation of ethylene and benzene, water-gas shift reaction, and oxidation of n-butyl sulfide. [References: 36]