End group analysis accounts for the low molecular weight observed in the 1,3-divinyltetramethyldisiloxane-Pt complex catalyzed hydrosilylation copolymerization of α,ω-dienes and 1,3-dihydridotetramethyldisiloxane

摘要

The 1,3-divinyltetramethyldisiloxane-Pt complex (Karstedt catalyst) facilitates copolymerization of α,ω-dienes, such as 1,7-octadiene or 1,5-hexadiene, with 1,3-dihydridotetramethyldisiloxane. Spectroscopic analysis of the copolymers indicates the presence dimethylsiloxy and either 2-octenyl or 2-hexenyl end groups. Apparently, the catalyst not only facilitates the hydrosilylation reaction of 1,3-dihydridotetramethyldisiloxane with terminal C-C double bonds but also catalyzes the isomerization of terminal alkenes to internal alkenes, which are not reactive.