Optical resolution of chirally functionalized [60]fullerene through formation of diastereomeric methoxyphenylacetic acid esters

Isobe Hiroyuki; Nakamura Eiichi; Sawamura Masaya

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Optical resolution of chirally functionalized [60]fullerene through formation of diastereomeric methoxyphenylacetic acid esters

机译：通过形成非对映异构的甲氧基苯基乙酸酯，对手性官能化的[60]富勒烯进行光学拆分

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摘要

Optical resolution of chirally functionalized [60]fullerene has been achieved through formation of diastereomeric α-methoxyphenylacetic acid (MPA) esters. The diastereomeric ester products were easily separated either by open column silica gel chromatography or by high pressure liquid chromatography (HPLC) with BuckyPrep column.

机译：通过形成非对映异构的α-甲氧基苯基乙酸（MPA）酯，可以实现手性官能化的[60]富勒烯的光学拆分。非对映体酯产物可以通过开管硅胶色谱法或带有BuckyPrep柱的高压液相色谱法（HPLC）轻松分离。

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《Fullerene science and technology》 |1999年第4期|共10页
作者
Isobe Hiroyuki; Nakamura Eiichi; Sawamura Masaya;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Fullerenes; Esters; Optical resolving power; Chemical modification; Gel permeation chromatography; High pressure liquid chromatography; Silica gel; Diastereomeric methoxyphenylacetic acid; Open column silica gel chromatography;

机译：富勒烯;酯;光学拆分能力;化学改性;凝胶渗透色谱;高压液相色谱;硅胶;非对映体甲氧基苯基乙酸;开柱硅胶色谱;

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1. Optical resolution of chirally functionalized [60]fullerene through formation of diastereomeric methoxyphenylacetic acid esters [J] . Isobe Hiroyuki, Nakamura Eiichi, Sawamura Masaya Fullerene science and technology . 1999,第4期

机译：通过形成非对映异构的甲氧基苯基乙酸酯，对手性官能化的[60]富勒烯进行光学拆分
2. Synthesis and optical resolution of an allenoic acid by diastereomeric salt formation induced by chiral alkaloids [J] . Nyhlen J, Eriksson L, Backvall JE Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2008,第1期

机译：通过手性生物碱诱导的非对映异构体盐的形成来合成烯丙酸并进行光学拆分
3. Iodo-controlled selective formation of pyrrolidino[60]fullerene and aziridino[60]fullerene from the reaction between C-60 and amino acid esters [J] . Zhang X, Gan LB, Huang SH, The Journal of Organic Chemistry . 2004,第17期

机译：从C-60与氨基酸酯的反应中碘控制的吡咯烷基[60]富勒烯和叠氮基[60]富勒烯的选择性形成
4. Chiral Discrimination of the Diastereomeric Salts with (R)-Nipecotic acid and Tartaric acid Derivative [C] . SUN Xiaoxia, LI Yingchun, ZHUANG Xiaoxiao International Conference on Chemical Engineering and Advanced Materials . 2013

机译：用（R）-Nipecotic酸和酒石酸衍生物的非对映体盐的手性辨别
5. I. Synthesis of alpha-amino acid esters. Dynamic kinetic resolution of zirconaaziridines with an optically active carbon dioxide synthon. II. Mechanism of alpha-amino amidine formation from zirconaaziridines and carbodiimides. [D] . Tunge, Jon Alan. 2000

机译：I.α-氨基酸酯的合成。氧化锆氮杂环丁烷与旋光二氧化碳合成子的动态动力学拆分。二。由氧化锆氮丙啶和碳二亚胺形成α-氨基am的机理。
6. Access to Optically Pure β-Hydroxy Esters via Non-Enzymatic Kinetic Resolution by a Planar-Chiral DMAP Catalyst [O] . Alba E. Díaz-Álvarez, Laura Mesas-Sánchez, Peter Dinér 2014

机译：平面手性DMAP催化剂通过非酶促动力学拆分获得光学纯的β-羟基酯
7. Iodo-Controlled Selective Formation of Pyrrolidino60fullerene and Aziridino60fullerene from the Reaction between C60 and Amino Acid Esters [O] . -1

机译：从C60和氨基酸酯之间的反应中，碘对照选择性形成Pyrrolidino60fullerene和Aziridino60fullerente

Optical resolution of chirally functionalized [60]fullerene through formation of diastereomeric methoxyphenylacetic acid esters

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