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Effect of residence time on fullerene yield

机译:停留时间对富勒烯产率的影响

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摘要

Although there exists no general agreement on mechanistic pathways for fullerene formation, there are some reasonable schemes in the literature explaining most of the features. However, as far as the existing production processes and the final yields are concerned, not the formation but rather chemical stabilization of the relatively hot products was more influence on the final production yield. A continuous helium jet was blown into the reactive zone by a quartz microprobe located 20 mm away from the are to enhance rapid removal of the products from the high temperature zone. Decreased residence times appear to improve production efficiency. [References: 15]
机译:尽管关于富勒烯形成的机制途径尚无普遍共识,但文献中有一些合理的方案可解释大多数特征。但是,就现有生产工艺和最终产量而言,相对热的产品不是形成而是化学稳定,这对最终产量的影响更大。连续的氦气射流通过位于距反应区20 mm处的石英微探针吹入反应区,以增强从高温区快速去除产物的能力。减少停留时间似乎可以提高生产效率。 [参考:15]

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