Plasma methane conversion in the presence of carbon dioxide using dielectric-barrier discharges

摘要

Methane conversion in the presence of carbon dioxide was investigated under the conditions of dielectric-barrier discharge plasmas. Different from the previous investigations, the grounded electrode is covered by the dielectric material (quartz) in the present reactor design. The product contains gaseous hydrocarbons, syngas and oxygenates. No liquid hydrocarbons can be detected with the present reactor design. The oxygenates produced includes acetic acid, propanoic acid, ethanol and methanol. There exists an optimum feed ratio of CH_4/CO_2 to make the maximum selectivity of the objective oxygenate. The highest selectivity of acetic acid 5.2% achieved at CH_4 and CO_2 conversions of 64.3% and 43.1% respectively.