Correlation between ultrasonic velocity, surface tension, density and viscosity of ionic liquids

摘要

Ultrasonic velocity, density, viscosity and surface tension of ionic liquids 1-butyl-3-methyl imadazolium hexafluorophosphate [BMIM][PF6], 1-butyl-3-methyl imadazolium octyl sulfate [BMIM][OcSO_4] and 1-ethyl-3-methyl imadazolium methane sulfonate [EMIM][MeSO_3] have been measured from 303K to 333K. Using these experimental data, inter relationships among ultrasonic velocity, density, viscosity and surface tension have been examined for these ionic liquids. It has been found that (a) ultrasonic velocity (u), surface tension (σ) and density (ρ) can be correlated linearly using equation, logu=ψlog σ/ρ+ξ (with typical values of ψ=1.61 and ξ=10.459) (b) surface tension is linearly correlated with viscosity by the relation ln σ=lna+bη~(-0.125), where ln a and b are constants. These correlations among physicochemical properties of the ionic liquids can be used to evaluate the properties (viz. ultrasonic velocity) not available in literature.