Vapor-liquid equilibria and excess volumes of the binary systems ethanol plus ethyl lactate, isopropanol plus isopropyl lactate and n-butanol plus n-butyl lactate at 101.325 kPa

摘要

Isobaric vapor-liquid equilibrium data have been experimentally determined at 101.3 kPa for the binary systems ethanol + ethyl lactate, isopropanol + isopropyl lactate and n-butanol + n-butyl lactate. No azeotrope was found in any of the systems. All the experimental data reported were thermodynamically consistent according to the point-to-point method of Fredenslund. The activity coefficients were correlated with the NRTL and UNIQUAC liquid-phase equations and the corresponding binary interaction parameters are reported. The densities and derived excess volumes for the three mixtures are also reported at 298.15 K. © 2005 Elsevier B.V. All rights reserved.