Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria. Part 4. The chemical model of Fe(III) with the halide ligands in aqueous solution at 25 °C

摘要

The Modified Bromley's Methodology (MBM) has been used to construct the basic chemical model between Fe(III) and OH~- and the halide ligands Cl~-, Br~- and F~- in NaClO_4 medium at 25 °C, obtaining the thermodynamic constants and the corresponding interaction parameters for each equilibrium. This basic model has been extended to KNO_3, HCl, and KCl media obtaining the corresponding interaction parameters. The applicability of the model is also discussed.