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The nature of the colloidal 'glass' transition

机译:胶体“玻璃”转变的性质

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摘要

The dynamically arrested state of matter is discussed in the context of athermal systems,such as the hard sphere colloidal arrest.We believe that the singular dynamical behaviour near arrest expressed,for example,in how the diffusion constant vanishes may be 'universal',in a sense to be discussed in the paper.Based on this we argue the merits of studying the problem with simple lattice models.This,by analogy with the the critical point of the Ising model,should lead us to clarify the questions,and begin the program of establishing the degree of universality to be expected.We deal only with 'ideal' athermal dynamical arrest transitions,such as those found for hard sphere systems.However,it is argued that dynamically available volume(DAV)is the relevant order parameter of the transition,and that universal mechanisms may be well expressed in terms of DAV.For simple lattice models we give examples of simple laws that emerge near the dynamical arrest,emphasising the idea of a near-ideal gas of'holes',interacting to give the power law diffusion constant scaling near the arrest.We also seek to open the discussion of the possibility of an underlying weak coupling theory of the dynamical arrest transition,based on DAV.
机译:在非热系统的背景下讨论了物质的动态停滞状态,例如硬球体的胶体停滞。我们认为,接近停滞的奇异动力学行为表现为,例如,扩散常数如何消失可能是“普遍的”。在此基础上,我们提出了用简单的格模型研究问题的优点。这类似于伊辛模型的临界点,应该使我们澄清问题,并开始研究问题。我们只处理“理想的”非热动力学停滞过渡,例如在硬球系统中发现的过渡。但是,有人认为动态有效体积(DAV)是相关的有序参数。对于简单的晶格模型,我们给出了在动态阻滞附近出现的简单定律的例子,强调了近理想气体的概念。我们还试图对基于DAV的动态阻滞过渡的潜在弱耦合理论的可能性进行讨论。

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