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Copper-Containing Catalyst with Fixed Active Component on an Alumina-Silica Carrier

机译:氧化铝-二氧化硅载体上具有固定活性成分的含铜催化剂

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It was found that the low thermal stability of commercial copper-containing catalyst (BASF Company) is associated with the chemical non-fixing of the active component on the surface of the silica carrier, while the degradation of its strength is due to the phase transition of the SiO2 carrier (alpha-quartz) into alpha-cristobalite. A thermally stable copper-containing catalyst MAK-K with an active component firmly bound with an alumina-silica carrier is proposed and studied. Experimental tests of the catalysts for thermal stability show that at 350A degrees C the relative activity of the catalyst N3-11 decreases by 41%, while the relative activity of the catalyst MAK-K changes by only 15%.
机译:已发现,商用含铜催化剂(BASF公司)的低热稳定性与活性成分在化学性质上不固定在二氧化硅载体表面有关,而其强度下降是由于相变SiO2载体(α-石英)转变为α-方石英。提出并研究了具有与氧化铝-二氧化硅载体牢固结合的活性组分的热稳定的含铜催化剂MAK-K。催化剂的热稳定性实验测试表明,在350A摄氏度下,催化剂N3-11的相对活性降低了41%,而催化剂MAK-K的相对活性仅改变了15%。

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