Selective gas-solid phase fixation of carbon dioxide into oxirane-containing polymers: synthesis of polymer bearing cyclic carbonate group

摘要

Gas-solid phase fixation of carbon dioxide into oxirane-containing polymers proceeds selectively without concomitant crosslinking reactions, which have previously been unavoidable due to the dense arrangement of oxirane groups. The fixation reaction obeys first-order kinetics, supporting the selectivity of the reaction.