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Temperature Brodadening of Vibrational Lines in Glasses

机译:玻璃中振动线的温度溴化

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摘要

The shape of vibrational lines and the temperature dependences of their width for structures with short-range and medium-range orders in oxide glasses have been studied.The relationship describing the contour of the line associated with internal vibrations of glass-forming polyhedra is derived in the framework of the model for deformation broadening of the vibrational spectra of two-level systems.It is found that the line within the width is represented by a Lorentzian contour,and the line wings decay as (#omega#-#omega#_0)~(-4).It is demonstrated that a similar contour is observed for the lines corrwesponding to the intrinsic vibrations of clusters with hingedbonds,which form the boson peak.The shape of teh line at 806 cm~(-1) for vitreous boron oxide,which is calculated in the framework of the propsed model,is in complete agreement with the experimental data in the temperature range 80-1900 K.
机译:研究了氧化物玻璃中短程和中程结构振动线的形状及其宽度的温度依赖性,推导了描述与形成玻璃的多面体内部振动相关的线轮廓关系。两级系统振动谱变形展宽模型的框架。发现宽度内的线由洛伦兹轮廓表示,线翼衰减为(#omega#-#omega#_0) 〜(-4)。结果表明,与铰链键团簇的固有振动相对应的线具有相似的轮廓,从而形成玻色子峰。玻璃硼在806 cm〜(-1)处的线形在支撑模型的框架内计算得出的氧化物与80-1900 K温度范围内的实验数据完全吻合。

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