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Degree of Polymerization of the CaAl_2Si_2O_8 Aluminosilicate Glass

机译:CaAl_2Si_2O_8铝硅酸盐玻璃的聚合度

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摘要

The pressure dependence of the refractive index for a glass of the composition 0.50SiO_2 centre dot 0.25Al_2O_3 centre dot 0.25CaO at pressures up to 5.0 GPa is determined using a polarizing interference microscope and an apparatus with diamond anvils.The densities and compressibilities of the glass are calculated from the measured refractive indices within the framework of the theory of photoelasticity.The results are compared with the data obtained earlier for vitreous silica.The lower compressibility of the glass under investigation as compared to the compressibility of fused silica is in agreement with the degree of polymerization that is calculated with due regard for the formation of triclusters from the relationship NBO/T = (2O +3O_t - 4T)/T,where NBO (nonbridg-ing oxygen)is the number of nonbridging oxygen atoms;O is the number of gram-ions of oxygen,except for of tricluster oxygen;O_t is the number of gram-ions of tricluster oxygen;and T is the total number of gram-ions of network formers.
机译:使用偏光干涉显微镜和带金刚石砧的设备确定了组成为0.50SiO_2中心点0.25Al_2O_3中心点0.25CaO的玻璃在高达5.0 GPa的压力下的折射率与压力的关系。玻璃的密度和可压缩性在光弹性理论的框架内根据测得的折射率计算得出的结果与之前获得的玻璃态二氧化硅的数据进行了比较。与熔融二氧化硅的可压缩性相比,所研究玻璃的可压缩性较低,与玻璃的可压缩性相符。根据关系NBO / T =(2O + 3O_t-4T)/ T计算的三聚体的形成的聚合度,其中NBO(非桥连氧)是非桥连氧原子的数目; O是氧的克离子数,除三聚体氧之外; O_t是三聚体氧的克数; T是净克的总数上班族。

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