Hydrothermal Synthesis and Crystal Structure of A Three-Dimensional Open-Framework Tin(II) Phosphate,[H2DACO]_(0.5)~(2+)[Sn4(PO4)3]~-

摘要

Open-framework materials,especially those of metal phosphates,have been of great interest in the past few years because of their potential applications in catalysis,sorption,ion-exchange processes and other areas,and also due to the fascinating structural features exhibited by them. Continued research in this area has shown that these materials are generally prepared under hydrothermal conditions in the presence of structure-directing organic amines (templates).