1D Coordination Polymer {[Zn(L1)(H2pm)]H2O}n: An Unusual Coordination of 1,5-COO- Groups of H2pm to Zinc(II) Ions

摘要

Macrocyclic transition metal complexes with polycarbox-ylate ligands have been proved to be good building blocks for the construction of coordination polymers and supra-molecular networks.Coordination polymers are generally composed of metal ion 'connectors' and multidentate ligand 'linkers',and the dimensionality of coordination polymers can be tuned by controlling the coordination sites of metal ion 'connectors' for multidentate ligand 'linkers'.