首页> 外文期刊>Bulletin of the Korean Chemical Society >Preparation of Gelatin-assisted Polypyrrole-Poly(3,4-ethylenedioxythiophene) Composites
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Preparation of Gelatin-assisted Polypyrrole-Poly(3,4-ethylenedioxythiophene) Composites

机译:明胶辅助的聚吡咯-聚(3,4-乙撑二氧噻吩)复合材料的制备

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摘要

Conductive polymer composite was synthesized by the polymerization of pyrrole with 3,4-ethylenedioxythiophene using ammonium persulfate as an oxidant with different concentrations of gelatin dispersed in aqueous medium along with the polymerization. Differently from pure polypyrrole-poly(3,4-ethylenedioxythiophene) (PPy-PEDOT) copolymer, the gelatin-assisted composites showed good solubility in aqueous media. The prepared PPy-PEDOT/gelatin composites were identified with Fourier-transform infrared, UV-visible spectroscopy, and X-ray diffraction. Morphological analysis and temperature-dependent direct current conductivity of PPy-PEDOT/gelatin composites were carried out. Obtained results revealed that added gelatin greatly increased conductivity due to the improved mobility of charge carriers.
机译:使用过硫酸铵作为氧化剂,将吡咯与3,4-乙二氧基噻吩聚合,并在聚合反应过程中,将不同浓度的明胶分散在水性介质中,从而合成导电聚合物复合材料。与纯聚吡咯-聚(3,4-乙撑二氧噻吩)(PPy-PEDOT)共聚物不同,明胶辅助的复合材料在水性介质中显示出良好的溶解性。制备的PPy-PEDOT /明胶复合材料通过傅立叶变换红外,紫外可见光谱和X射线衍射进行鉴定。进行了PPy-PEDOT /明胶复合材料的形态分析和温度依赖性直流电导率。获得的结果表明,由于电荷载流子的迁移率提高,添加的明胶极大地提高了电导率。

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