Formation of Complex XeHCl~+in the Xe~++HC1 Collision

摘要

The formation of complex XeHCl~+in the collision-induced reaction of Xe~+with HC1 has been studied by use of classical dynamics procedures using the London-Eyring-Polanyi-Sato empirical potential energy surfaces.A small fraction of trajectories on the Xe~++HC1 and Xe+HQ~+surfaces lead to the formation of complex XeHCl~+with life-times of 1-2 ps which is long enough to survive many rotations before redissociating back to the reactant state.The formation of complex XeHCl~+occurs mainly from collision angle of 0=45°.