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A Facile and Efficient Deoxygenation of Sulfoxides with Mo(CO)6

机译:Mo(CO)6对亚砜的快速高效脱氧

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摘要

The deoxygenation of sulfoxides to sulfides is a valuable transformation in the application of organosulfur compounds in organic synthesis.Accordingly,a good number of methods have been developed for the reduction of sulfoxides to the corresponding sulfides.However,they often suffer from serious disadvantages,such as functional group incompatibility,difficult work-up procedures,harsh reaction conditions,or not readily available reagents.
机译:亚砜脱氧成硫化物是有机硫化合物在有机合成中的应用中有价值的转变。因此,已经开发出许多方法将亚砜还原成相应的硫化物。然而,它们经常遭受严重的不利因素,例如由于官能团不相容,后处理程序困难,反应条件苛刻或试剂不易获得。

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