An Efficient Synthesis of α,α-Diallyl Carbinols from Esters Activated with Amides via an In-Mediated Barbier Type Allylation

摘要

Allylindium reagents have been used extensively for the introduction of allyl group in a Barbier type manner to various electrophiles." Although many reactive electrophiles such as aldehydes and imines have been used in the indium-mediated allylations, the reactions of allylindium reagents with less reactive nitriles and esters have not been reported much.